Preferential Scattering by Interfacial Charged Defects for Enhanced Thermoelectric Performance in Few-layered n-type Bi[subscript 2]Te[subscript 3]
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Puneet-2013-Preferential Scatter.pdf
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Author(s)
Puneet, Pooja
Podila, Ramakrishna
Karakaya, Mehmet
Zhu, Song
He, Jian
Tritt, Terry M.
Rao, Apparao M.
Dresselhaus, Mildred
Date Issued
November 2013
Journal
Scientific Reports
Publisher
Nature Publishing Group
Citation
Puneet, Pooja, Ramakrishna Podila, Mehmet Karakaya, Song Zhu, Jian He, Terry M. Tritt, Mildred S. Dresselhaus, and Apparao M. Rao. “Preferential Scattering by Interfacial Charged Defects for Enhanced Thermoelectric Performance in Few-Layered n-Type Bi2Te3.” Sci. Rep. 3 (November 14, 2013).
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Original manuscript
Abstract
Over the past two decades several nano-structuring methods have helped improve the figure of merit (ZT) in the state-of-the art bulk thermoelectric materials. While these methods could enhance the thermoelectric performance of p-type Bi[subscript 2]Te[subscript 3], it was frustrating to researchers that they proved ineffective for n-type Bi[subscript 2]Te[subscript 3] due to the inevitable deterioration of its thermoelectric properties in the basal plane. Here, we describe a novel chemical-exfoliation spark-plasma-sintering (CE-SPS) nano-structuring process, which transforms the microstructure of n-type Bi[subscript 2]Te[subscript 3] in an extraordinary manner without compromising its basal plane properties. The CE-SPS processing leads to preferential scattering of electrons at charged grain boundaries, and thereby increases the electrical conductivity despite the presence of numerous grain boundaries, and mitigates the bipolar effect via band occupancy optimization leading to an upshift (by ~ 100 K) and stabilization of the ZT peak over a broad temperature range of ~ 150 K.
MIT Department
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Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
Massachusetts Institute of Technology. Department of Physics
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DOI of Published Version
https://doi.org/10.1038/srep03212
