Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands
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Author(s)
Bruno, Nicholas C.
Buchwald, Stephen Leffler
Date Issued
May 2013
Journal
Organic Letters
Publisher
American Chemical Society (ACS)
Citation
Bruno, Nicholas C., and Stephen L. Buchwald. “Synthesis and Application of Palladium Precatalysts That Accommodate Extremely Bulky Di- Tert -Butylphosphino Biaryl Ligands.” Org. Lett. 15, no. 11 (June 7, 2013): 2876–2879.
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Author's final manuscript
Abstract
A series of palladacyclic precatalysts that incorporate electron-rich di-tert-butylphosphino biaryl ligands is reported. These precatalysts are easily prepared, and their use provides a general means of employing bulky ligands in palladium-catalyzed cross-coupling reactions. The application of these palladium sources to various C–N and C–O bond-forming processes is also described.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1021/ol401208t
