Functionalized Templates for the Convergent Assembly of Polyethers: Synthesis of the HIJK Rings of Gymnocin A
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Jamison_Functionalized templates.pdf
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380.55 KB
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Author(s)
Van Dyke, Aaron R.
Jamison, Timothy F.
Date Issued
May 2009
Journal
Angewandte Chemie International Edition
Publisher
Wiley Blackwell
Citation
Van Dyke, Aaron R., and Timothy F. Jamison. “Functionalized Templates for the Convergent Assembly of Polyethers: Synthesis of the HIJK Rings of Gymnocin A.” Angewandte Chemie International Edition 48, no. 24 (June 2, 2009): 4430-4432.
Version
Author's final manuscript
Abstract
Extension ladder: The successful application of epoxide-opening strategies towards the synthesis of ladder-type polyethers is contingent upon further elaboration of the product. By employing two different functionalized templates, a fragment of gymnocin A that bears four sites for subsequent fragment coupling has been prepared (see scheme; Bn=benzyl).
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Creative Commons Attribution-Noncommercial-Share Alike 3.0
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DOI of Published Version
https://doi.org/10.1002/anie.200900924
