Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit
Name
Angew Chem Int Ed - 2022 - Kampouri - Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building.pdf
Description
Published version
Size
2.42 MB
Format
Adobe PDF
Checksum (MD5)
d0b7a67a57b86974ea1b2762d6011a28
Author(s)
Kampouri, Stavroula
Zhang, Mingxuan
Chen, Tianyang
Oppenheim, Julius J
Brown, Alexandra
Payne, Michael
Andrews, Justin L
Sun, Junliang
Dincă, Mircea
Date Issued
2022
Journal
Angewandte Chemie - International Edition
Publisher
Wiley
Citation
Kampouri, Stavroula, Zhang, Mingxuan, Chen, Tianyang, Oppenheim, Julius J, Brown, Alexandra et al. 2022. "Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit." Angewandte Chemie - International Edition, 61 (49).
Version
Final published version
Abstract
We report a metal-organic framework (MOF) with a rare two-dimensional (2D) secondary building unit (SBU). The SBU comprises mixed-valent Fe2+ and Fe3+ metal ions bridged by oxygen atoms pertaining to the polytopic ligand 3,3',4,4',5,5'-hexahydroxybiphenyl, which also define the iron-oxide 2D layers. Overall, the anionic framework exhibits rare topology and evidences strong electronic communication between the mixed-valence iron sites. These results highlight the importance of dimensionality control of MOF SBUs for discovering new topologies in reticular chemistry, and especially for improving electronic communication within the MOF skeleton.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Creative Commons Attribution-NonCommercial-NoDerivs License
Persistent DSpace Link
DOI of Published Version
https://doi.org/10.1002/ANIE.202213960
