Heavy p-type carbon doping of MOCVD GaAsP using CBrCl₃
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CHeidelberger_GaAsP_C_Doping_Final_Manuscript.pdf
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Author(s) •
Heidelberger, Christopher
Fitzgerald, Eugene A
Date Issued
May 2016
Journal
Journal of Crystal Growth
Publisher
Elsevier
Citation
Heidelberger, Christopher, and Eugene A. Fitzgerald. “Heavy p-type carbon doping of MOCVD GaAsP using CBrCl₃.” Journal of Crystal Growth 446 (July 2016): 7–11.
Version
Author's final manuscript
Abstract
CBrCl₃ is shown to be a useful precursor for heavy p-type carbon doping of GaAsxP1−x grown via metalorganic chemical vapor deposition (MOCVD) across a range of compositions. Structural and electrical properties of the GaAsP films were measured for various processing conditions. Use of CBrCl3 decreased the growth rate of GaAsP by up to 32% and decreases x by up to 0.025. The dependence of these effects on precursor inputs is investigated, allowing C-doped GaAsP films to be grown with good thickness and compositional control. Hole concentrations of greater than 2×10¹⁹ cm−3 were measured for values of x from 0.76 to 0.90.
MIT Department
Lincoln Laboratory
Massachusetts Institute of Technology. Department of Materials Science and Engineering
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Creative Commons Attribution-NonCommercial-NoDerivs License
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DOI of Published Version
https://doi.org/10.1016/j.jcrysgro.2016.04.028