Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole
Name
nihms956512.pdf
Description
Accepted version
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3.62 MB
Format
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fb7ca506491457a28992348a93b718fc
Author(s)
Truong, Tran N. B
Savagatrup, Suchol
Jeon, Intak
Swager, Timothy M
Date Issued
June 2018
Journal
Journal of polymer science. Part A, Polymer chemistry
Publisher
Wiley
Citation
Truong, Tran N. B. et al. “Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole.” Journal of polymer science. Part A, Polymer chemistry 56 (2018): 1133-1139 © 2018 The Author(s)
Version
Author's final manuscript
Abstract
A modular and facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show high thermal stability and solubility in a number of solvents. Characterization of the polymers reveals a correlation between molecular packing, controllable by polymer design, and charge carrier mobility.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Massachusetts Institute of Technology. Department of Materials Science and Engineering
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Creative Commons Attribution-Noncommercial-Share Alike
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DOI of Published Version
https://doi.org/10.1002/POLA.28990
