Dependence of the ocean-atmosphere partitioning of carbon on temperature and alkalinity
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Omtaetal_GBC_2011.pdf
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Author(s)
Omta, Anne Willem
Dutkiewicz, Stephanie
Follows, Michael J
Date Issued
January 2011
Journal
Global Biogeochemical Cycles
Publisher
American Geophysical Union (AGU)
Citation
Omta, Anne Willem et al. “Dependence of the Ocean-Atmosphere Partitioning of Carbon on Temperature and Alkalinity.” Global Biogeochemical Cycles 25, 1 (January 2011): GB1003 © 2011 American Geophysical Union
Version
Final published version
Abstract
We develop and extend a theoretical framework to analyze the impacts of changes in temperature and alkalinity on the ocean-atmosphere carbon partitioning. When investigating the impact of temperature, we assume that there is no change in the global ocean alkalinity. This idealized situation is probably most relevant on intermediate timescales of hundreds to thousands of years. Our results show that atmospheric pCO₂ depends approximately exponentially on the average ocean temperature, since the chemical equilibria involved have an exponential (Arrhenius-type) dependence. The dependence of pCO₂ on alkalinity is more complicated, and our theory suggests several regimes. The current ocean-atmosphere system appears to have an exponential dependence of pCO₂ on global mean ocean alkalinity, but at slightly higher alkalinities, the dependence becomes a power law. We perform experiments with a numerical physical-biogeochemical model to test the validity of our analytical theory in a more complex, ocean-like system: in general, the numerical results support the analytical inferences.
MIT Department
Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1029/2010GB003839
