Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines
Name
Movassaghi_Concise total.pdf
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3.65 MB
Format
Adobe PDF
Checksum (MD5)
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Author(s)
Han, Sunkyu
Movassaghi, Mohammad
Date Issued
June 2011
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Han, Sunkyu, and Mohammad Movassaghi. “Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines.” Journal of the American Chemical Society 133, no. 28 (July 20, 2011): 10768-10771.
Version
Author's final manuscript
Abstract
The concise and enantioselective total syntheses of (−)-trigonoliimines A, B, and C are described. Our unified strategy to all three natural products is based on asymmetric oxidation and reorganization of a single bistryptamine, a sequence of transformations with possible biogenetic relevance. We revise the absolute stereochemistry of (−)-trigonoliimines A, B, and C.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ja204597k
