Endo-Selective Enyne Ring- Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes
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Author(s)
Zhao, Yu
Hoveyda, Amir H.
Schrock, Richard Royce
Date Issued
January 2011
Journal
Organic Letters
Publisher
American Chemical Society
Citation
Zhao, Yu, Amir H. Hoveyda, and Richard R. Schrock. “Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes.” Organic Letters 13.4 (2011): 784–787.
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Author's final manuscript
Abstract
The utility of W-alkylidene complexes for enyne ring-closing metathesis is demonstrated in a direct comparison with Mo-based analogs. Tungsten complexes lead to less alkyne oligomerization and higher levels of endo-selectivity and enantioselectivity.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ol1030525
