Coordination-induced reversible electrical conductivity variation in the MOF-74 analogue Fe[subscript 2](DSBDC)
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c8dt02197j.pdf
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Author(s)
Hendon, Christopher H.
Sun, Lei
Dinca, Mircea
Date Issued
July 2018
Journal
Dalton Transactions
Publisher
Royal Society of Chemistry
Citation
Sun, Lei, et al. “Coordination-Induced Reversible Electrical Conductivity Variation in the MOF-74 Analogue Fe[subscript 2](DSBDC).” Dalton Transactions, 2018.
Version
Final published version
Abstract
Inner-sphere changes at the open Fe centers in Fe[subscript 2](DSBDC) (DSBDC[superscript 4-] = 2,5-disulfidobenzene-1,4-dicarboxylate), as caused by coordination and release of solvent molecules, lead to reversible structural and electrical conductivity changes. Specifically, coordination of N,N-dimethylformamide (DMF) to the open Fe sites improves the room-temperature electrical conductivity by three orders of magnitude. Supported by additional density functional theory calculations, we attribute the electrical conductivity enhancement to partial electron transfer from Fe to DMF, which generates hole carriers and improves the charge carrier density in Fe[subscript 2](DSBDC).
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Creative Commons Attribution-NonCommercial 3.0 Unported
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DOI of Published Version
https://doi.org/10.1039/C8DT02197J
