Quantitative assessment of the frictional ignition resistance of
metals in high-pressure oxygen
Name
GarciaJimenez-garciaji-SM-AeroAstro-2023-thesis.pdf
Description
Thesis PDF
Size
5.4 MB
Format
Adobe PDF
Checksum (MD5)
0220e2ff431bb7c443bb04edead9007d
Author(s)
Garcia Jimenez, Andres
Advisor(s)
Cordero, Zachary C.
Date Issued
June 2023
Publisher
Massachusetts Institute of Technology
Abstract
In this work, we developed a material index for selecting alloys resistant to frictional ignition in high-pressure oxygen environments. A previous ignition-resistance metric proposed by NASA WSTF varies strongly and unpredictably with test conditions, thus limiting its usefulness. The material index developed here incorporates key material properties that influence ignition behaviors, including friction coefficient, ignition temperature, and thermal effusivity. Finite element simulations were used to compute ignition temperatures for 15 alloys based on published frictional ignition data from NASA White Sands Testing Facility (WSTF). These values were used with the material index to construct property diagrams for ranking intrinsic frictional ignition resistance. The results demonstrate that nickel-based superalloys with low iron content are less likely to ignite under frictional heating than ferrous alloys and nickel-based superalloys with high content iron. The material index is then used to predict material performance outside of the test conditions, highlighting the effect of ambient temperature on ignition resistance. We conclude by developing an empirical relation between ignition temperature and enthalpy of oxidation which can guide the design of new ignition-resistant alloys.
MIT Department
Massachusetts Institute of Technology. Department of Aeronautics and Astronautics
Terms of Use
Attribution 4.0 International (CC BY 4.0)
Copyright retained by author(s)
Persistent DSpace Link
