A Multi-Ligand Based Pd Catalyst for C–N Cross-Coupling Reactions
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Author(s)
Fors, Brett P.
Buchwald, Stephen Leffler
Date Issued
October 2010
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Fors, Brett P., and Stephen L. Buchwald. “A Multiligand Based Pd Catalyst for C−N Cross-Coupling Reactions.” Journal of the American Chemical Society 132.45 (2010): 15914–15917.
Version
Author's final manuscript
Abstract
An alternative approach to catalyst development, which led to a Pd catalyst based on two biarylphosphine ligands for C−N cross-coupling reactions, is reported. By effectively being able to take the form of multiple catalysts this system manifests the best properties that catalysts based on either of the two ligands exhibit separately and displays the highest reactivity and substrate scope of any system that has been reported to date for these reactions.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ja108074t
