Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion
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McKinley_Linker-free grafting.pdf
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Author(s)
Sojoudi, Hossein
McKinley, Gareth H.
Gleason, Karen K.
Date Issued
October 2014
Journal
Materials Horizons
Publisher
Royal Society of Chemistry
Citation
Sojoudi, Hossein, Gareth H. McKinley, and Karen K. Gleason. “Linker-Free Grafting of Fluorinated Polymeric Cross-Linked Network Bilayers for Durable Reduction of Ice Adhesion.” Mater. Horiz. (2014).
Version
Final published version
Abstract
Thin films of bilayer poly(divinyl benzene) p(DVB)/poly(perfluorodecylacrylate) (p-PFDA) are synthesized via iCVD on steel and silicon substrates. Nanomechanical measurements reveal that the elastic modulus and hardness of the films are enhanced through the bilayer structure and that the adhesion of the films to the substrate is improved via in situ grafting mechanism. The strength of ice adhesion to the treated surfaces is reduced more than six-fold when the substrates are coated with these bilayer polymer networks.
MIT Department
Massachusetts Institute of Technology. Department of Chemical Engineering
Massachusetts Institute of Technology. Department of Mechanical Engineering
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DOI of Published Version
https://doi.org/10.1039/c4mh00162a
