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Ionic thermoelectric materials for near ambient temperature energy harvesting

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Author(s)
Liu, Weishu
•
Qian, Xin
•
Han, Cheng-Gong
•
Li, Qikai
•
Chen, Gang
Date Issued
January 11, 2021
Journal
Applied Physics Letters
Publisher
AIP Publishing
Citation
Weishu Liu, Xin Qian, Cheng-Gong Han, Qikai Li, Gang Chen; Ionic thermoelectric materials for near ambient temperature energy harvesting. Appl. Phys. Lett. 11 January 2021; 118 (2): 020501.
Version
Final published version
Abstract
Ionic thermoelectric (i-TE) materials, using ions as the energy carrier, can generate a voltage under a temperature difference, bearing similarities to the Seebeck effect of electrons and holes in solid-state materials. Recent experiments have demonstrated large thermopower of quasi-solid-state i-TE materials, which are attractive for harvesting ambient heat as large enough voltage can be generated under a small temperature difference to match the voltage input needs of sensors for internet-of-things applications. In this perspective article, we discuss similarities and differences of i-TE materials from electronic-based thermoelectric materials and also different i-TE thermoelectric effects including the thermodiffusion (Soret) effect and the thermogalvanic effect, in which the latter includes redox reaction entropy and the Soret effect. Strategies to improve performances of materials and devices are elaborated, together with needs for future research in understanding microscopic origins of different effects.
MIT Department
Massachusetts Institute of Technology. Department of Mechanical Engineering
Terms of Use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Persistent DSpace Link
https://hdl.handle.net/1721.1/165243
DOI of Published Version
10.1063/5.0032119
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