Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions
Name
Strieth-Kalthoff_et_al-2018-ChemCatChem.pdf
Description
Published version
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918.57 KB
Format
Adobe PDF
Checksum (MD5)
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Author(s)
Strieth-Kalthoff, Felix
Longstreet, Ashley R.
Weber, Jessica Marie
Jamison, Timothy F
Date Issued
July 2018
Journal
ChemCatChem
Publisher
Wiley
Citation
Strieth-Kalthoff, Felix, et al., "Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions." ChemCatChem 10, 13 (July 2018): p. 2873-77 doi 10.1002/CCTC.201800454 ©2018 Author(s)
Version
Final published version
Abstract
Herein, we introduce a new class of bench-stable N-heterocyclic carbene (NHC) nickel-precatalysts for homogeneous nickel-catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed Heck-type mechanism. The precatalysts are shown to facilitate carbonyl-ene, hydroalkenylation, and amination reactions.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Creative Commons Attribution 4.0 International license
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DOI of Published Version
https://doi.org/10.1002/CCTC.201800454
