A Ligand Exchange Process for the Diversification of Palladium Oxidative Addition Complexes
Name
nihms-1736006.pdf
Description
Accepted version
Size
1.15 MB
Format
Adobe PDF
Checksum (MD5)
4593b8203184cbac823873d29e013362
Author(s)
King, Ryan P
Krska, Shane W
Buchwald, Stephen L
Date Issued
2021
Journal
Organic Letters
Publisher
American Chemical Society (ACS)
Citation
King, Ryan P, Krska, Shane W and Buchwald, Stephen L. 2021. "A Ligand Exchange Process for the Diversification of Palladium Oxidative Addition Complexes." Organic Letters, 23 (15).
Version
Author's final manuscript
Abstract
Palladium oxidative addition complexes (OACs) have recently emerged as useful tools to enable challenging bond connections. However, each OAC can only be formed with one dative ligand at a time. As no one ligand is optimal for every cross-coupling reaction, we herein disclose a ligand exchange protocol for the preparation of a series of OACs bearing a variety of ancillary ligands from one common complex. These complexes were further applied to cross-coupling transformations.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Creative Commons Attribution-Noncommercial-Share Alike
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DOI of Published Version
https://doi.org/10.1021/ACS.ORGLETT.1C02101
