Variations in grain boundary segregation for nanocrystalline stability and strength
Name
821070517-MIT.pdf
Description
Full printable version
Size
3.16 MB
Format
Adobe PDF
Checksum (MD5)
bfe7959781a27c117818c239a322d426
Author(s)
Figueroa, Oscar, III
Advisor(s)
Christopher Schuh.
Date Issued
2012
Publisher
Massachusetts Institute of Technology
Abstract
In the last few decades, nanocrystalline metals have been of increasing interest. Their ability to show increased yield strength and uniform structure show them to be potentially useful in many applications. Additionally, nanocrystalline metals have become more easily manufactured in recent years, allowing for more testing and more use within industrial settings. However, nanocrystalline metals are still highly unstable, mainly due to temperature related growth. Grain boundary segregation is one way in which materials can keep nano length-scale grains. This process involves metal alloys that preferentially segregate the alloying material to the grain boundaries, potentially leading to Grain Boundary Embrittlement (GBE). Using an ideal work of fracture equation, [gamma] = 2[sigma]s - [sigma]g, the energy required to fracture nanocrystalline metal alloys was obtained, and predicted grain stability. Fracture toughness data is also calculated and compared. A contrast between bulk and nanocrystalline alloys is then made, showing benefits to the use of either set of materials for specific alloy functions.
Description
Thesis (S.B.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2012.
Cataloged from PDF version of thesis.
Includes bibliographical references (p. 39).
Subjects
Materials Science and Engineering.
MIT Department
Massachusetts Institute of Technology. Department of Materials Science and Engineering
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