Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides
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Buchwald_Ligand-controlled.pdf
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Author(s)
Yang, Yang
Buchwald, Stephen Leffler
Date Issued
July 2013
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Yang, Yang, and Stephen L. Buchwald. “Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides.” Journal of the American Chemical Society 135, no. 29 (July 24, 2013): 10642–10645.
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Author's final manuscript
Abstract
An orthogonal set of catalyst systems has been developed for the Suzuki–Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ja405950c
