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Quantifying the Drivers of Ocean-Atmosphere CO₂ Fluxes

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Author(s)
Williams, Richard G.
•
Lauderdale, Jonathan
•
Dutkiewicz, Stephanie
•
Follows, Michael J
Date Issued
July 2016
Journal
Global Biogeochemical Cycles
Publisher
American Geophysical Union (AGU)
Citation
Lauderdale, Jonathan M. et al. “Quantifying the Drivers of Ocean-Atmosphere CO₂ Fluxes.” Global Biogeochemical Cycles 30, 7 (July 2016): 983–999 © 2016 The Authors
Version
Final published version
Abstract
A mechanistic framework for quantitatively mapping the regional drivers of air-sea CO₂ fluxes at a global scale is developed. The framework evaluates the interplay between (1) surface heat and freshwater fluxes that influence the potential saturated carbon concentration, which depends on changes in sea surface temperature, salinity and alkalinity, (2) a residual, disequilibrium flux influenced by upwelling and entrainment of remineralized carbon- and nutrient-rich waters from the ocean interior, as well as rapid subduction of surface waters, (3) carbon uptake and export by biological activity as both soft tissue and carbonate, and (4) the effect on surface carbon concentrations due to freshwater precipitation or evaporation. In a steady state simulation of a coarse-resolution ocean circulation and biogeochemistry model, the sum of the individually determined components is close to the known total flux of the simulation. The leading order balance, identified in different dynamical regimes, is between the CO₂ fluxes driven by surface heat fluxes and a combination of biologically driven carbon uptake and disequilibrium-driven carbon outgassing. The framework is still able to reconstruct simulated fluxes when evaluated using monthly averaged data and takes a form that can be applied consistently in models of different complexity and observations of the ocean. In this way, the framework may reveal differences in the balance of drivers acting across an ensemble of climate model simulations or be applied to an analysis and interpretation of the observed, real-world air-sea flux of CO₂.
MIT Department
Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences
Terms of Use
Creative Commons Attribution 4.0 International License
http://creativecommons.org/licenses/by/4.0/
Persistent DSpace Link
http://hdl.handle.net/1721.1/118376
DOI of Published Version
https://doi.org/10.1002/2016GB005400
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