Interdigitated conducting tetrathiafulvalene-based coordination networks
Name
C9CC09960C.pdf
Description
Accepted version
Size
611.97 KB
Format
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Checksum (MD5)
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Author(s)
Bechu, Damien
Xie, Lilia S.
Le Breton, Nolwenn
Choua, Sylvie
Dinca, Mircea
Hosseini, Mir Wais
Baudron, Stéphane A.
Date Issued
January 2020
Journal
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Citation
Bechu, Damien et al. "Interdigitated conducting tetrathiafulvalene-based coordination networks." Chemical Communications 56, 16 (January 2020): 2407-2410 © 2020 The Royal Society of Chemistry
Version
Author's final manuscript
Abstract
Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10[superscript -6] vs. 10[superscript -12] S cm[superscript -1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Creative Commons Attribution-Noncommercial-Share Alike
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DOI of Published Version
https://doi.org/10.1039/c9cc09960c
