Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction
Name
A review of inorganic with SI.pdf
Size
3.17 MB
Format
Adobe PDF
Checksum (MD5)
a7e4256baaa3f235dc058f160937e504
Author(s)
Lux, Simon F.
Paschos, Odysseas
Maglia, Filippo
Lupart, Saskia
Lamp, Peter
Bachman, Chris
Muy, Sokseiha
Grimaud, Alexis
Chang, Hao Hsun
Pour, Nir
Alternative Title
Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction
Date Issued
December 2015
Journal
Chemical Reviews
Publisher
American Chemical Society (ACS)
Citation
Bachman, John Christopher, Sokseiha Muy, Alexis Grimaud, Hao-Hsun Chang, Nir Pour, Simon F. Lux, Odysseas Paschos, et al. “Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction.” Chemical Reviews 116, no. 1 (January 13, 2016): 140–162.
Version
Author's final manuscript
Abstract
This Review is focused on ion-transport mechanisms and fundamental properties of solid-state electrolytes to be used in electrochemical energy-storage systems. Properties of the migrating species significantly affecting diffusion, including the valency and ionic radius, are discussed. The natures of the ligand and metal composing the skeleton of the host framework are analyzed and shown to have large impacts on the performance of solid-state electrolytes. A comprehensive identification of the candidate migrating species and structures is carried out. Not only the bulk properties of the conductors are explored, but the concept of tuning the conductivity through interfacial effects—specifically controlling grain boundaries and strain at the interfaces—is introduced. High-frequency dielectric constants and frequencies of low-energy optical phonons are shown as examples of properties that correlate with activation energy across many classes of ionic conductors. Experimental studies and theoretical results are discussed in parallel to give a pathway for further improvement of solid-state electrolytes. Through this discussion, the present Review aims to provide insight into the physical parameters affecting the diffusion process, to allow for more efficient and target-oriented research on improving solid-state ion conductors.
MIT Department
MIT Materials Research Laboratory
Massachusetts Institute of Technology. Department of Materials Science and Engineering
Massachusetts Institute of Technology. Department of Mechanical Engineering
Massachusetts Institute of Technology. Research Laboratory of Electronics
Terms of Use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Persistent DSpace Link
DOI of Published Version
https://doi.org/10.1021/acs.chemrev.5b00563
