Uranium–Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex
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bnu_jacs_030509.pdf
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Author(s)
Fox, Alexander R.
Cummins, Christopher C.
Date Issued
December 2008
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society
Citation
Fox, Alexander R., and Christopher C. Cummins. “Uranium−Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex.” Journal of the American Chemical Society 131.16 (2009) : 5716-5717.
Version
Author's final manuscript
Abstract
While uranium imido complexes are well established in the
literature, complexes featuring a uranium nitride functionality
are rare. Data pertaining to terminal uranium nitrides are
limited to the spectroscopic observation of the binary uranium
nitrides UN and NUN and the ternary nitride NUF[subscript 3] under
matrix conditions. We are interested in the uranium nitride
functional group as it incorporates metal-ligand multiple
bonding, valence f orbitals, and redox activity.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ja8095812
