Proof of Tacticity of Stereoregular ROMP Polymers through Post Polymerization Modification
Name
Schrock_Proof of Tacticity with SI.pdf
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2.05 MB
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Author(s)
Hyvl, Jakub
Autenrieth, Benjamin
Schrock, Richard Royce
Date Issued
April 2015
Journal
Macromolecules
Publisher
American Chemical Society (ACS)
Citation
Hyvl, Jakub; Autenrieth, Benjamin and Schrock, Richard R."Proof of Tacticity of Stereoregular ROMP Polymers through Post Polymerization Modification." Macromolecules 48, no. 9 (May 2015): 3148–3152. © 2015 American Chemical Society
Version
Author's final manuscript
Abstract
Partial bromination or epoxidation has been used to prove the tacticities of several stereoregular polymers made through ROMP methods with well-defined Mo or W initiators.Tacticities were proven for cis,isotactic and cis,syndiotactic poly(norbornene), poly(3-methyl-3-phenylcyclopropene), and poly(endo,anti-tetracyclododecene). Various limitations can prevent application of these proofs in general to stereoregular polymers prepared through ROMP.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/acs.macromol.5b00477
