Quantum diamonds : a discussion of the chemistry, materials science, physics and applications of ternary (Cu-In-S) nanocrystals
Name
1102048205-MIT.pdf
Size
5.47 MB
Format
Adobe PDF
Checksum (MD5)
e527e2929e3cf89d3c64916a2fd9accb
Author(s)
Romero, Trevor Walton.
Advisor(s)
Juejun Hu.
Alternative Title
Discussion of the chemistry, materials science, physics and applications of ternary (Cu-In-S) nanocrystals
Date Issued
2019
Publisher
Massachusetts Institute of Technology
Abstract
Quantum dots (QDs) are nanometer-sized crystallites of inorganic semiconductors with tunable optoelectronic properties, which has led to a variety of real-world applications beginning in the 1980s, ranging including electronic displays, solar cells, and quantum computers [(Lee, SID), (Tang, Nature Mater.), (Puri, Phys Rev. B)]. However, most high-quality QD materials explored to date have been limited for large-scale application due to toxicity concerns or difficult-to-scale preparative methods. This thesis explores the synthesis and properties of colloidal nanocrystals composed of the non-toxic semiconductor copper indium sulfide (CulnS₂). We report an improved core nanoparticle synthesis with unique compositional control, a rationally-designed precursor for the synthesis of high-quality CulnS₂/ZnS nanocomposites, and describe the dependence on the photophysical properties of CulnS₂/ZnS on core CulnS₂ elemental composition.
Description
Thesis: S.B., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2019
Cataloged from PDF version of thesis.
Includes bibliographical references (pages 33-34).
Subjects
Materials Science and Engineering.
MIT Department
Massachusetts Institute of Technology. Department of Materials Science and Engineering
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