Impact of Processing Environment on Anti-Solvent Free FAPbI3 Films and Solar Cells
Name
Advanced Energy Materials - 2025 - Wall - Impact of Processing Environment on Anti‐Solvent Free FAPbI3 Films and Solar.pdf
Description
Published version
Size
2.69 MB
Format
Adobe PDF
Checksum (MD5)
72da492443a4d73d350803cef7109b5c
Author(s)
Wall, Elizabeth M
Lin, Yu‐Kuan
Bawendi, Moungi
Burlingame, Quinn C
Loo, Yueh‐Lin
Date Issued
December 17, 2025
Journal
Advanced Energy Materials
Publisher
Wiley
Citation
Wall, Elizabeth M, Lin, Yu‐Kuan, Bawendi, Moungi, Burlingame, Quinn C and Loo, Yueh‐Lin. 2025. "Impact of Processing Environment on Anti-Solvent Free FAPbI3 Films and Solar Cells." Advanced Energy Materials, 16 (7).
Version
Final published version
Abstract
As perovskite solar cells approach commercialization, understanding the environmental sensitivities of perovskites during fabrication becomes increasingly important. In this work, the humidity-dependence of each deposition and annealing step in the anti-solvent-free two-step formamidinium lead iodide fabrication process is investigated in air and N2. In-situ grazing-incidence wide-angle X-ray scattering measurements during spin-coating indicate that humidity affects the formation and dynamics of intermediate phases in perovskite precursor films. These differences, and those induced by annealing in humidity, impact the structure, morphology, and composition of resultant perovskite films, though the initial performance of solar cells fabricated using these active layers is relatively insensitive to humidity across the range studied. In contrast, stability is maximized in devices with dry-processed active layers and those terminally annealed in humidity. Spin-coating of PbI2 is most environmentally sensitive—needle-like structures precipitate while spin-coating in 40% relative humidity leading to significantly reduced photovoltaic performance and device stability. Additionally, films and solar cells fabricated in air appear virtually identical to those fabricated in N2. Collectively, these results show that optimal performance and stability of two-step processed formamidinium lead iodide solar cells is achieved when fabricating active layers in a dry atmosphere or with some humidity during the final anneal.
MIT Department
Massachusetts Institute of Technology. Department of Materials Science and Engineering
Massachusetts Institute of Technology. Department of Chemistry
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Creative Commons Attribution
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DOI of Published Version
10.1002/aenm.202503828
