Synthesis and Properties of the 5,10,15-Trimesityltruxen-5-yl Radical
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Author(s)
Frantz, Derik K.
Walish, Joseph John
Swager, Timothy Manning
Date Issued
August 2013
Journal
Organic Letters
Publisher
American Chemical Society (ACS)
Citation
Frantz, Derik K., Joseph J. Walish, and Timothy M. Swager. “Synthesis and Properties of the 5,10,15-Trimesityltruxen-5-Yl Radical.” Org. Lett. 15, no. 18 (September 20, 2013): 4782–4785.
Version
Author's final manuscript
Abstract
The synthesis of a long-lived, truxene-based radical that is highly delocalized and exhibits a narrow EPR absorption is reported. The radical is stable for multiple hours in a solution exposed to air and remains for months in the solid state under inert gas. Characterization and properties are discussed.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1021/ol402153w
