Direct β-Selective Hydrocarboxylation of Styrenes with CO₂ Enabled by Continuous Flow Photoredox Catalysis
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Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis .pdf
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585.86 KB
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Author(s)
Seo, Hyowon
Liu, Aofei
Jamison, Timothy F
Date Issued
October 2017
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Seo, Hyowon et al. “Direct β-Selective Hydrocarboxylation of Styrenes with CO₂ Enabled by Continuous Flow Photoredox Catalysis.” Journal of the American Chemical Society 139, 40 (September 2017): 13969–13972 © 2017 American Chemical Society
Version
Author's final manuscript
Abstract
The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO₂ has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as α-substituted and β-substituted styrenes.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/jacs.7b05942
