General Approach to Epipolythiodiketopiperazine Alkaloids: Total Synthesis of (+)-Chaetocins A, C and (+)-12,12'- Dideoxychetracin A
Name
Movassaghi_General Approach.pdf
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1.44 MB
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Adobe PDF
Checksum (MD5)
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Author(s)
Kim, Justin
Movassaghi, Mohammad
Date Issued
September 2010
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society
Citation
Kim, Justin, and Mohammad Movassaghi. “General Approach to Epipolythiodiketopiperazine Alkaloids: Total Synthesis of (+)-Chaetocins A and C and (+)-12,12'-Dideoxychetracin A.” Journal of the American Chemical Society 132.41 (2010): 14376–14378.
Version
Author's final manuscript
Abstract
A highly stereoselective and systematic strategy for the introduction of polysulfides in the synthesis of epipolythiodiketopiperazines is described. We report the first total synthesis of dimeric epitri- and epitetrathiodiketopiperazines.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ja106869s
