Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
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Buchwald_Palladium-Catalyzed.pdf
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679.07 KB
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Author(s)
Shen, Xiaoqiang
Hyde, Alan M.
Buchwald, Stephen Leffler
Date Issued
2010
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Shen, Xiaoqiang, Alan M. Hyde, and Stephen L. Buchwald. “Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides.” Journal of the American Chemical Society 132.40 (2010): 14076–14078.
Version
Author's final manuscript
Abstract
The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in good to excellent yields.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/ja107481a
