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Atomically sharp interlayer stacking shifts at anti-phase grain boundaries in overlapping MoS 2 secondary layers
Name
C8NR04486D.pdf
Description
Accepted version
Size
3.23 MB
Format
Adobe PDF
Checksum (MD5)
9f6acc4019e924ea14f9ea61fed0aaea
Author(s)
Zhou, Si
Wang, Shanshan
Shi, Zhe
Sawada, Hidetaka
Kirkland, Angus I
Li, Ju
Warner, Jamie H
Date Issued
2018
Journal
Nanoscale
Publisher
Royal Society of Chemistry (RSC)
Version
Author's final manuscript
Abstract
© The Royal Society of Chemistry 2018. When secondary domains nucleate and grow on the surface of monolayer MoS2, they can extend across grain boundaries in the underlying monolayer MoS2 and form overlapping sections. We present an atomic level study of overlapping antiphase grain boundaries (GBs) in MoS2 monolayer-bilayers using aberration-corrected annular dark field scanning transmission electron microscopy. In particular we focus on the antiphase GB within a monolayer and track its propagation through an overlapping bilayer domain. We show that this leads to an atomically sharp interface between 2H and 3R interlayer stacking in the bilayer region. We have studied the micro-nanoscale "meandering" of the antiphase GB in MoS2, which shows a directional dependence on the density of 4 and 8 member ring defects, as well as sharp turning angles 90°-100° that are mediated by a special 8-member ring defect. Density functional theory has been used to explore the overlapping interlayer stacking around the antiphase GBs, confirming our experimental findings. These results show that overlapping secondary bilayer MoS2 domains cause atomic structure modification to underlying anti-phase GB sites to accommodate the van der Waals interactions.
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Creative Commons Attribution-Noncommercial-Share Alike
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DOI of Published Version
10.1039/C8NR04486D
