Asymmetric linker generates intrinsically disordered metal–organic framework with local MOF-74 structure
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d5cc03713a.pdf
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Published version
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Author(s)
Dinakar, Bhavish
Oppenheim, Julius J
Vandone, Marco
Torres, Juan F
Iliescu, Andrei
Yang, Zhentao
Román-Leshkov, Yuriy
Dincă, Mircea
Date Issued
August 14, 2025
Journal
Chemical Communications
Publisher
Royal Society of Chemistry
Citation
Dinakar, Bhavish, Oppenheim, Julius J, Vandone, Marco, Torres, Juan F, Iliescu, Andrei et al. 2025. "Asymmetric linker generates intrinsically disordered metal–organic framework with local MOF-74 structure." Chemical Communications, 61 (67).
Version
Final published version
Abstract
Here, we report an intrinsically disordered MOF in the MOF-74 family,
Mg2x(as-dobpdc) (as-dobpdc4 = 30
,4-dioxidobiphenyl-3,40
-dicarboxylate). Despite the absence of crystallinity, this material exhibits
local ordering consistent with that of its crystalline isomers, maintains
porosity, and exhibits a high density of open metal sites.
MIT Department
Massachusetts Institute of Technology. Department of Chemical Engineering
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1039/d5cc03713a
