Radical synthesis of trialkyl, triaryl, trisilyl and tristannyl phosphines from P₄
Name
main_revised.pdf
Description
Main article
Size
574.93 KB
Format
Adobe PDF
Checksum (MD5)
97acc07fd9d623ad36bce3d4397a43d3
Author(s)
Cossairt, Brandi M.
Cummins, Christopher C.
Date Issued
April 2010
Journal
New Journal of Chemistry
Publisher
RSC Publishing
Citation
Cossairt, Brandi M., and Christopher C. Cummins. “Radical Synthesis of Trialkyl, Triaryl, Trisilyl and Tristannyl Phosphines from P4.” New Journal of Chemistry 34.8 (2010) : 1533.
Version
Author's final manuscript
Abstract
A reaction scheme has been devised according to 3 RX + 3 Ti(III) + 0.25 P₄ → PR₃ + 3 XTi(IV), wherein RX = PhBr, CyBr, Me₃SiI or Ph₃SnCl, with contrasting results in the case of more hindered RX. The scheme accomplishes the direct radical functionalization of white phosphorus without the intermediacy of PCl₃.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Terms of Use
Creative Commons Attribution-Noncommercial-Share Alike 3.0
Persistent DSpace Link
DOI of Published Version
https://doi.org/10.1039/c0nj00124d
