Shuttling P(3) [P subscript 3] from Niobium to Rhodium: The Synthesis and Use of Ph(3)SnP(3)(C(6)H(8)) [Ph subscript 3 Sn P subscript 3 (C subscript 6 H subscript 8)] as a P(3) (-) [P subscript 3 superscript 1-] Synthon
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manuscript.pdf
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Main article
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Author(s)
Cossairt, Brandi M.
Cummins, Christopher C.
Date Issued
January 2010
Journal
Angewandte Chemie International Edition
Publisher
Gesellschaft Deutscher Chemiker / Wiley
Citation
Cossairt, Brandi M., and Christopher C. Cummins. “Shuttling P 3 from Niobium to Rhodium: The Synthesis and Use of Ph 3 SnP 3 (C 6 H 8 ) as a P 3 − Synthon.” Angewandte Chemie International Edition (2010) : NA-NA. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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Author's final manuscript
Abstract
Anatomy of a P3− [P subscript 3 superscript -] synthon: The Ph3SnP3(C6H8) [Ph subscript 3 Sn P subscript 3 (C subscript 6 H subscript 8)] molecule (see picture; Sn red, P orange) has been synthesized by triphosphorus transfer from a niobium complex. This molecule was shown to be a viable source of P3− [P subscript 3 superscript -] in a proof-of-principle reaction: loss of Ph3SnCl [Ph subscript 3 SnCl] and 1,3-cyclohexadiene from Ph3SnP3(C6H8) [Ph subscript 3 Sn P subscript 3 (C subscript 6 H subscript 8)] upon treatment with Wilkinson's catalyst, [ClRh(PPh3)3] [[ClRh(PPh subscript 3) subscript 3]], gives rise to the new cyclo-P3 [cyclo-P subscript 3] complex [(η3-P3)Rh(PPh3)3] [[(eta superscript 3 - P subscript 3) Rh (PPh subscript 3) subscript 3]].
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1002/anie.200906633
