Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
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Buchwald_An improved palladium.pdf
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Author(s) • • •
Pan, Jun
Wang, Xinyan
Zhang, Yong
Buchwald, Stephen Leffler
Alternative Title
An Improved Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
Date Issued
August 2011
Journal
Organic Letters
Publisher
American Chemical Society (ACS)
Citation
Pan, Jun, Xinyan Wang, Yong Zhang, and Stephen L. Buchwald. “An Improved Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides.” Organic Letters 13, no. 18 (September 16, 2011): 4974-4976.
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Author's final manuscript
Abstract
A facile Pd-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) is described. This method allows convenient access to a variety of aryl, heteroaryl, and vinyl halides in good to excellent yields and with greatly simplified conditions relative to our previous report.
MIT Department
MIT Materials Research Laboratory
Massachusetts Institute of Technology. Department of Chemistry
Sloan School of Management
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DOI of Published Version
https://doi.org/10.1021/ol202098h