Acetonitrile based single step slot-die compatible perovskite ink for flexible photovoltaics
Name
c9ra06631d.pdf
Description
Published version
Size
1.71 MB
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Adobe PDF
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Author(s) • • • • • • •
Burkitt, Daniel
Swartwout, Richard M
McGettrick, James
Greenwood, Peter
Beynon, David
Brenes, Roberto
Bulović, Vladimir
Watson, Trystan
Date Issued
November 2019
Journal
RSC Advances
Publisher
Royal Society of Chemistry (RSC)
Citation
Burkitt, Daniel et al. "Acetonitrile based single step slot-die compatible perovskite ink for flexible photovoltaics." RSC Advances 9, 64 (November 2019): 37415-37423 © 2019 Royal Society of Chemistry
Version
Final published version
Abstract
The demonstration of photovoltaic devices with high power conversion efficiencies using low cost perovskite materials hints at the possibility of dramatically lowering the cost of solar energy. Key to further exploiting the potential of these materials is developing rapid processing techniques that can be used to deliver lower cost high throughput manufacture. This work details the development of low viscosity rapid drying perovskite formulations designed to give high quality solar films when slot-die coated on flexible roll-to-roll compatible substrates. A single step slot-die compatible perovskite ink based on an acetonitrile/methylamine solvent system utilizing a chloride additive is developed, resulting in large area perovskite films from slot-die coating under ambient conditions. The drying conditions for the perovskite film are optimized and fast (<10 min), low temperature (<120 °C) drying of slot-die coated films on flexible substrates are demonstrated and result in high performance devices.
MIT Department
Massachusetts Institute of Technology. Research Laboratory of Electronics
Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
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Creative Commons Attribution 3.0 unported license
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DOI of Published Version
https://doi.org/10.1039/c9ra06631d