Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature
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Swager_Red Phosphorescence.pdf
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Author(s)
Gutierrez, Gregory D.
Sazama, Graham T.
Wu, Tony C
Baldo, Marc A
Swager, Timothy M
Date Issued
June 2016
Journal
The Journal of Organic Chemistry
Publisher
American Chemical Society (ACS)
Citation
Gutierrez, Gregory D., Graham T. Sazama, Tony Wu, Marc A. Baldo, and Timothy M. Swager. “Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature.” The Journal of Organic Chemistry 81, no. 11 (June 3, 2016): 4789–4796. doi:10.1021/acs.joc.6b00789.
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Author's final manuscript
Abstract
We describe the red phosphorescence exhibited by a class of structurally simple benzo[2,1,3]thiadiazoles at room temperature. The photophysical properties of these molecules in deoxygenated cyclohexane, including their absorption spectra, steady-state photoluminescence and excitation spectra, and phosphorescence lifetimes, are presented. Time-dependent density functional theory calculations were carried out to better understand the electronic excited states of these benzo[2,1,3]thiadiazoles and why they are capable of phosphorescence.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
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DOI of Published Version
https://doi.org/10.1021/acs.joc.6b00789
