Catalytic Addition of Simple Alkenes to Carbonyl Compounds by Use of Group 10 Metals
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Jamison_Catalytic addition.pdf
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Author(s)
Ho, Chun-Yu
Chan, Chun-Wa
Schleicher, Kristin D.
Jamison, Timothy F.
Date Issued
September 2009
Journal
Synlett
Publisher
Thieme Publishing Group
Citation
Ho, Chun-Yu, Kristin Schleicher, Chun-Wa Chan, and Timothy Jamison. “Catalytic Addition of Simple Alkenes to Carbonyl Compounds by Use of Group 10 Metals.” Synlett 2009, no. 16 (October 4, 2009): 2565-2582.
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Author's final manuscript
Abstract
Recent advances using nickel complexes in the activation of unactivated monosubstituted olefins for catalytic intermolecular carbon-carbon bond-forming reactions with carbonyl compounds, such as simple aldehydes, isocyanates, and conjugated aldehydes and ketones, are discussed. In these reactions, the olefins function as vinyl- and allylmetal equivalents, providing a new strategy for organic synthesis. Current limitations and the outlook for this new strategy are also discussed.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Creative Commons Attribution-Noncommercial-Share Alike 3.0
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DOI of Published Version
https://doi.org/10.1055/s-0029-1217747
