Continuous ion-selective separation by shock electrodialysis
Name
1103318158-MIT.pdf
Size
25.44 MB
Format
Adobe PDF
Checksum (MD5)
2095a699704e614395a5687708bcc216
Author(s)
Conforti, Kameron Michael.
Advisor(s)
Martin Z. Bazant and Cullen R. Buie.
Date Issued
2019
Publisher
Massachusetts Institute of Technology
Abstract
Cleaning water remains a challenge across sectors and across the globe. Many go without access to clean drinking water simply because the technologies that exist are too expensive in capital or energy. Areas thought to have reliably safe water can be betrayed by aging water infrastructure and exposed to hazardous contaminants. In addition to the need to purify drinking water is the necessity to treat waste water produced by chemical or energy plants. For a long time, reverse osmosis has been used as a catch-all technology for the robust treatment of contaminated water. That robustness comes as the cost of high energy requirements and membranes that can foul quickly under harsh conditions. For low-salinity separations or separations that target specific ions in solution, there may be a better technological fit. In this thesis, shock electrodialysis (SED) is demonstrated to achieve highly selective continuous removal of magnesium ions from an aqueous mixture of NaCl and MgCl₂.
To explore this phenomena, the SED device has all of its inputs and outputs characterized to determine internal flows of fluid and ions. This careful study provides valuable insight into the mechanisms that drive selectivity, current efficiency, and desalination, as well as potential methods to improve performance. The selectivity comes as a result of the deionization shock and associated depletion region in a negatively charged porous frit. For solutions initially rich in sodium and dilute in magnesium, high (> 98%) removal of magnesium can be achieved with only moderate (50-70%) removal of total salt. Dilute lead is also shown to be selectively removed from a mixture of NaCl and PbCl₂. A high removal of lead (90%) can be achieved at very low total desalination (< 25%). The final section of this thesis covers work on a related electrochemical technology that also utilizes current applied perpendicular to flow: flow batteries.
A membraneless hydrogen bromine flow battery is developed, achieving record cycles and power density for a membraneless flow system.
Description
Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2019
Cataloged from PDF version of thesis.
Includes bibliographical references (pages 155-163).
Subjects
Chemical Engineering.
MIT Department
Massachusetts Institute of Technology. Department of Chemical Engineering
Terms of Use
MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission.
Persistent DSpace Link
