Synthesis of a Water-Soluble 1,3-Bis(diphenylene)2-phenylallyl Radical
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526.53 KB
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Author(s)
Swager, Timothy Manning
Dane, Eric L.
Date Issued
April 2010
Journal
Journal of Organic Chemistry
Publisher
American Chemical Society (ACS)
Citation
Dane, Eric L., and Timothy M. Swager. “Synthesis of a Water-Soluble 1,3-Bis(diphenylene)-2-phenylallyl Radical.” The Journal of Organic Chemistry 75.10 (2010): 3533–3536.
Version
Author's final manuscript
Abstract
The design and synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl (BDPA) radical via the conjugate addition of a derivatized fluorene nucelophile is described. The compound is designed for use in dynamic nuclear polarization NMR. Its 9 GHz EPR spectrum in glycerol/water is reported.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
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DOI of Published Version
https://doi.org/10.1021/jo100577g
