Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products
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Lippard_Non-heme.pdf
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Author(s)
Majumdar, Amit
Lippard, Stephen J.
Date Issued
November 2013
Journal
Inorganic Chemistry
Publisher
American Chemical Society (ACS)
Citation
Majumdar, Amit, and Stephen J. Lippard. “Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products.” Inorg. Chem. 52, no. 23 (December 2, 2013): 13292–13294.
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Author's final manuscript
Abstract
Mononitrosyldiiron complexes having either an [Fe[superscript II]·{FeNO}[superscript 7]] or an [Fe[superscript III]·{FeNO}[superscript 7]] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis, X-ray structures, Mössbauer spectroscopy, cyclic voltammetry, and dioxygen reactivity of [Fe[superscript III]·{FeNO}[superscript 7]] are described.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1021/ic4019508
