Challenges for Na-ion Negative Electrodes
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Ceder_Challenges for Na.pdf
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Author(s) •
Chevrier, Vincent L.
Ceder, Gerbrand
Date Issued
July 2011
Journal
Journal of The Electrochemical Society
Publisher
Electrochemical Society
Citation
Chevrier, V. L., and G. Ceder. Challenges for Na-ion Negative Electrodes. Journal of The Electrochemical Society 158, no. 9 (2011): A1011. © 2011 ECS - The Electrochemical Society.
Version
Final published version
Abstract
Na-ion batteries have been proposed as candidates for replacing Li-ion batteries. In this paper we examine the viability of Na-ion negative electrode materials based on Na alloys or hard carbons in terms of volumetric energy density. Due to the increased size of the Na atom compared to the Li atom, Na alloys would lead to negative electrode materials with roughly half the volumetric energy density of their Li analogs. Volumetric energy densities obtainable with sodiated hard carbons would also be significantly less than those obtainable with lithiated graphite. These findings highlight the need of novel ideas for Na-ion negative electrodes.
MIT Department
Massachusetts Institute of Technology. Department of Materials Science and Engineering
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DOI of Published Version
https://doi.org/10.1149/1.3607983