Dimerization of functional pyrroloindolizines for the synthesis of complex myrmicarin alkaloids
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Author(s)
Ondrus, Alison E.
Kaniskan, Husnu Umit
Movassaghi, Mohammad
Date Issued
April 2010
Journal
Tetrahedron
Publisher
Elsevier B.V.
Citation
Ondrus, Alison E., H. Ümit Kaniskan, and Mohammad Movassaghi. “Dimerization of Functional Pyrroloindolizines for the Synthesis of Complex Myrmicarin Alkaloids.” Tetrahedron 66.26 (2010): 4784–4795. Web.
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Author's final manuscript
Abstract
The union of functionalized pyrroloindolizines for the synthesis of heterodimeric products relevant to myrmicarin alkaloids is described. Design and synthesis of tricyclic substrates and new methods for their union enable the investigation of late-stage cyclopentannulation strategies. The rapid assembly of dimeric structures using unique modes of pyrroloindolizine reactivity presents a concise approach to the dimeric myrmicarins and relevant derivatives.
MIT Department
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
http://dx.doi.org/10.1016/j.tet.2010.04.006
