Lithium Manganese Spinel Cathodes for Lithium‐Ion Batteries
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document(1).pdf
Description
Accepted version
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2.42 MB
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Checksum (MD5)
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Author(s)
Huang, Yimeng
Dong, Yanhao
Li, Sa
Lee, Jinhyuk
Wang, Chao
Zhu, Zhi
Xue, Weijiang
Li, Yao
Li, Ju
Date Issued
2021
Journal
Advanced Energy Materials
Publisher
Wiley
Version
Author's final manuscript
Abstract
© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Spinel LiMn2O4, whose electrochemical activity was first reported by Prof. John B. Goodenough's group at Oxford in 1983, is an important cathode material for lithium-ion batteries that has attracted continuous academic and industrial interest. It is cheap and environmentally friendly, and has excellent rate performance with 3D Li+ diffusion channels. However, it suffers from severe degradation, especially under extreme voltages and during high-temperature operation. Here, the current understanding and future trends of the spinel cathode and its derivatives with cubic lattice symmetry (LiNi0.5Mn1.5O4 that shows high-voltage stability, and Li-rich spinels that show reversible hybrid anion- and cation-redox activities) are discussed. Special attention is given to the degradation mechanisms and further development of spinel cathodes, as well as concepts of utilizing the cubic spinel structure to stabilize high-capacity layered cathodes and as robust framework for high-rate electrodes. “Good spinel” surface phases like LiNi0.5Mn1.5O4 are distinguished from “bad spinel” surface phases like Mn3O4.
MIT Department
Massachusetts Institute of Technology. Department of Materials Science and Engineering
Massachusetts Institute of Technology. Department of Nuclear Science and Engineering
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DOI of Published Version
https://doi.org/10.1002/AENM.202000997
