Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes
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Author(s)
Maimone, Thomas
Su, Mingjuan
Chen, Jiahao
Milner, Phillip John
Mueller, Peter
Buchwald, Stephen Leffler
Date Issued
November 2012
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Milner, Phillip J., Thomas J. Maimone, Mingjuan Su, Jiahao Chen, Peter Müller, and Stephen L. Buchwald. “Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes.” Journal of the American Chemical Society 134, no. 48 (December 5, 2012): 19922–19934.
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Author's final manuscript
Abstract
A series of monoligated L·Pd[superscript II](Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented Pd[superscript II]-mediated insertion of an aryl group into an unactivated arene.
MIT Department
Massachusetts Institute of Technology. Computer Science and Artificial Intelligence Laboratory
Massachusetts Institute of Technology. Department of Chemistry
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DOI of Published Version
https://doi.org/10.1021/ja310351e
