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dc.contributor.authorMuralidhar, Ramachandran
dc.contributor.authorWaser, Rainer
dc.contributor.authorHan, Jihyung
dc.contributor.authorBazant, Martin Z
dc.date.accessioned2019-03-01T19:56:32Z
dc.date.available2019-03-01T19:56:32Z
dc.date.issued2016-10
dc.date.submitted2016-10
dc.identifier.issn0013-4686
dc.identifier.issn0019-4686
dc.identifier.urihttp://hdl.handle.net/1721.1/120666
dc.description.abstractSolid-state programmable metallization cells have attracted considerable attention as memristive elements for Redox-based Resistive Random Access Memory (ReRAM) for low-power and low-voltage applications. In principle, liquid-state metallization cells could offer the same advantages for aqueous systems, such as biomedical lab-on-a-chip devices, but robust resistive switching has not yet been achieved in liquid electrolytes, where electrodeposition is notoriously unstable to the formation of fractal dendrites. Here, the recently discovered physics of shock electrodeposition are harnessed to stabilize aqueous copper growth in polycarbonate nanopores, whose surfaces are modified with charged polymers. Stable bipolar resistive switching is demonstrated for 500 cycles with <10 s retention times, prior to any optimization of the geometry or materials. Keywords: shock electrodeposition; resistive switching; over-limiting current; charged nanopores; deionization shock waveen_US
dc.publisherElsevieren_US
dc.relation.isversionofhttp://dx.doi.org/10.1016/J.ELECTACTA.2016.10.188en_US
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivs Licenseen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en_US
dc.sourcearXiven_US
dc.titleResistive Switching in Aqueous Nanopores by Shock Electrodepositionen_US
dc.typeArticleen_US
dc.identifier.citationHan, Ji-Hyung et al. “Resistive Switching in Aqueous Nanopores by Shock Electrodeposition.” Electrochimica Acta 222 (December 2016): 370–375 © 2016 Elsevier Ltden_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemical Engineeringen_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Mathematicsen_US
dc.contributor.mitauthorHan, Jihyung
dc.contributor.mitauthorBazant, Martin Z
dc.relation.journalElectrochimica Actaen_US
dc.eprint.versionOriginal manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/NonPeerRevieweden_US
dc.date.updated2019-02-11T17:39:10Z
dspace.orderedauthorsHan, Ji-Hyung; Muralidhar, Ramachandran; Waser, Rainer; Bazant, Martin Z.en_US
dspace.embargo.termsNen_US
dc.identifier.orcidhttps://orcid.org/0000-0002-8200-4501
mit.licensePUBLISHER_CCen_US


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