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dc.contributor.advisorMartin Z. Bazant and Cullen R. Buie.en_US
dc.contributor.authorConforti, Kameron Michael.en_US
dc.contributor.otherMassachusetts Institute of Technology. Department of Chemical Engineering.en_US
dc.date.accessioned2019-07-18T20:27:31Z
dc.date.available2019-07-18T20:27:31Z
dc.date.copyright2019en_US
dc.date.issued2019en_US
dc.identifier.urihttps://hdl.handle.net/1721.1/121775
dc.descriptionThesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2019en_US
dc.descriptionCataloged from PDF version of thesis.en_US
dc.descriptionIncludes bibliographical references (pages 155-163).en_US
dc.description.abstractCleaning water remains a challenge across sectors and across the globe. Many go without access to clean drinking water simply because the technologies that exist are too expensive in capital or energy. Areas thought to have reliably safe water can be betrayed by aging water infrastructure and exposed to hazardous contaminants. In addition to the need to purify drinking water is the necessity to treat waste water produced by chemical or energy plants. For a long time, reverse osmosis has been used as a catch-all technology for the robust treatment of contaminated water. That robustness comes as the cost of high energy requirements and membranes that can foul quickly under harsh conditions. For low-salinity separations or separations that target specific ions in solution, there may be a better technological fit. In this thesis, shock electrodialysis (SED) is demonstrated to achieve highly selective continuous removal of magnesium ions from an aqueous mixture of NaCl and MgCl₂.en_US
dc.description.abstractTo explore this phenomena, the SED device has all of its inputs and outputs characterized to determine internal flows of fluid and ions. This careful study provides valuable insight into the mechanisms that drive selectivity, current efficiency, and desalination, as well as potential methods to improve performance. The selectivity comes as a result of the deionization shock and associated depletion region in a negatively charged porous frit. For solutions initially rich in sodium and dilute in magnesium, high (> 98%) removal of magnesium can be achieved with only moderate (50-70%) removal of total salt. Dilute lead is also shown to be selectively removed from a mixture of NaCl and PbCl₂. A high removal of lead (90%) can be achieved at very low total desalination (< 25%). The final section of this thesis covers work on a related electrochemical technology that also utilizes current applied perpendicular to flow: flow batteries.en_US
dc.description.abstractA membraneless hydrogen bromine flow battery is developed, achieving record cycles and power density for a membraneless flow system.en_US
dc.description.statementofresponsibilityby Kameron Michael Conforti.en_US
dc.format.extent163 pagesen_US
dc.language.isoengen_US
dc.publisherMassachusetts Institute of Technologyen_US
dc.rightsMIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission.en_US
dc.rights.urihttp://dspace.mit.edu/handle/1721.1/7582en_US
dc.subjectChemical Engineering.en_US
dc.titleContinuous ion-selective separation by shock electrodialysisen_US
dc.typeThesisen_US
dc.description.degreePh. D.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemical Engineeringen_US
dc.identifier.oclc1103318158en_US
dc.description.collectionPh.D. Massachusetts Institute of Technology, Department of Chemical Engineeringen_US
dspace.imported2019-07-18T20:27:28Zen_US
mit.thesis.degreeDoctoralen_US
mit.thesis.departmentChemEngen_US


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