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Bench-Stable Nickel Precatalysts with Heck-type Activation

Author(s)
Weber, Jessica M.; Longstreet, Ashley R.; Jamison, Timothy F
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Creative Commons Attribution 4.0 International license https://creativecommons.org/licenses/by/4.0/
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Abstract
Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl-ene coupling reaction.
Date issued
2018-08
URI
https://hdl.handle.net/1721.1/126128
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Organometallics
Publisher
American Chemical Society (ACS)
Citation
Weber, Jessica M., Ashley R. Longstreet, and Timothy F. Jamison. "Bench-Stable Nickel Precatalysts with Heck-type Activation." Organometallics 37, 16 (Aug. 2018): p. 2716-22 doi 10.1021/ACS.ORGANOMET.8B00351 ©2018 Author(s)
Version: Final published version
ISSN
0276-7333

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