Asymmetric linker generates intrinsically disordered metal–organic framework with local MOF-74 structure
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Here, we report an intrinsically disordered MOF in the MOF-74 family,
Mg2x(as-dobpdc) (as-dobpdc4 = 30
,4-dioxidobiphenyl-3,40
-dicarboxylate). Despite the absence of crystallinity, this material exhibits
local ordering consistent with that of its crystalline isomers, maintains
porosity, and exhibits a high density of open metal sites.
Date issued
2025-08-14Department
Massachusetts Institute of Technology. Department of Chemical Engineering; Massachusetts Institute of Technology. Department of ChemistryJournal
Chemical Communications
Publisher
Royal Society of Chemistry
Citation
Dinakar, Bhavish, Oppenheim, Julius J, Vandone, Marco, Torres, Juan F, Iliescu, Andrei et al. 2025. "Asymmetric linker generates intrinsically disordered metal–organic framework with local MOF-74 structure." Chemical Communications, 61 (67).
Version: Final published version