Phosphate-mineral interactions and potential consequences for nutrient cycling
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245049585-MIT.pdf
Description
Full printable version
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12.95 MB
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Author(s)
Oates, Richard Hunter
Advisor(s)
William Martin.
Date Issued
2008
Publisher
Massachusetts Institute of Technology
Abstract
Biogeochemical cycling of phosphate is a key component in the overall production rate of coastal ecosystems. Mineral phases in the near-shore sediments play a significant role in the return of phosphate remineralized in the upper sediments to the water column. Sequential Extraction (SEDEX) of the solid-phase associated P04-3 yielded reservoir profiles of phosphate at three sites off of the Massachusetts coast. These extractions found Fe-associated P04 to be the dominant phase associated with rapid porewater-solid P exchange. Additionally, a seasonal enrichment/depletion pattern of phosphate fluxes relative to total carbon was observed from the sediments. These observations established the behavior of phosphate in coastal sediments as interconnected with the ongoing Fe-cycling in the sediments as well.
Description
Thesis (S.M.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2008.
Includes bibliographical references (p. 45-47).
Subjects
Joint Program in Oceanography.
Earth, Atmospheric, and Planetary Sciences.
Woods Hole Oceanographic Institution.
MIT Department
Joint Program in Oceanography
Woods Hole Oceanographic Institution
Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences
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