| dc.contributor.advisor | Richard R. Shrock. | en_US |
| dc.contributor.author | O'Donoghue, Myra Brigid, 1966- | en_US |
| dc.contributor.other | Massachusetts Institute of Technology. Dept. of Chemistry. | en_US |
| dc.date.accessioned | 2010-01-07T20:51:16Z | |
| dc.date.available | 2010-01-07T20:51:16Z | |
| dc.date.copyright | 1999 | en_US |
| dc.date.issued | 1999 | en_US |
| dc.identifier.uri | http://hdl.handle.net/1721.1/50544 | |
| dc.description | Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 1999. | en_US |
| dc.description | Includes bibliographical references. | en_US |
| dc.description.abstract | { [N 3N]Mo-N=N} 2Mg(THF)2, isolated from the reduction of [N3N]MoCl by magnesium powder under dinitrogen, serves as an entry into the dinitrogen chemistry of molybdenum complexes containing the TMS-TREN ligand. ... Five coordinate tungsten oxo alkylidene complexes of the general type (ArO)2W(O)(CHtBu)(PR 3 ) (Ar = 2,6-Ph2C6H3 ) are synthesized by reaction of Ta(CHtBu)(PR 3)2X3 (X = Cl, Br) with W(O)(OtBu) 4. 1H NMR spectroscopy reveals that only the syn rotamer is present in solution and PPh2Me is labile on the NMR time scale. | en_US |
| dc.description.statementofresponsibility | by Myra Brigid O'Donoghue. | en_US |
| dc.format.extent | 178 leaves | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Massachusetts Institute of Technology | en_US |
| dc.rights | M.I.T. theses are protected by
copyright. They may be viewed from this source for any purpose, but
reproduction or distribution in any format is prohibited without written
permission. See provided URL for inquiries about permission. | en_US |
| dc.rights.uri | http://dspace.mit.edu/handle/1721.1/7582 | en_US |
| dc.subject | Chemistry. | en_US |
| dc.title | Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum | en_US |
| dc.type | Thesis | en_US |
| dc.description.degree | Ph.D. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.identifier.oclc | 43852050 | en_US |
